In Double and Triple Battles, you're able to choose Transform's target, provided the target is adjacent to the user. However, Imposter doesn't let you choose — it automatically turns the user into the Pokémon directly opposite it.
Transform (Bulbapedia) Imposter (Bulbapedia)
Transform: You can chose who to Transform into. Imposter: It will be randomized what you transform into.
Source: PO tested.