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I teamed up with Mira in Wayward cave to help with shiny hunting. I had my Sneasel in front, but I didn't get much encounters. Sometimes I would go a few minutes running around and not getting anything. Then, I switched my Empoleon to the front of my party, and encounters came a lot quicker. Is there an explanation for this? Does it have something to do with affection (My Sneasel has like, no affection while Empoleon loves me), am I just unlucky, does Mira hate shiny Sneasels, or is there another reason?

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Is this BDSP or DPP? :x

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From Pokémon Emerald onward, if a Pokémon with Keen Eye is in the first place in the party (even if fainted), there is a 50% chance it will prevent a random wild encounter that would have occurred if the wild Pokémon would be at least 5 levels lower than the Pokémon with Keen Eye. It shares this effect with Intimidate.

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Since Keen Eye is one of Sneasel's non Hidden Ability, it's likely that your Sneasel had this ability and while leading in front, it was 5 levels ahead of the wild Pokemon.

Therefore, it's because of Sneasel's ability Keen Eye's effect outside of battle, rather than being any affection related stuff. Hope this helps!

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Ah that explains it. My Sneasel does have Keen Eye. Thanks, I need to study up on out-of-battle ability effects...
No prob
E: This is DPP I'm assuming from the recent question you asked related to it?
Yeah this is DPP forgot to mention.