PokéBase - Pokémon Q&A
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You need to get your Eevee & Eeveelutions to an 80%+ Link. You can also catch Arceus to appear if you're in the Hero's episode at that point.

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all of Evee's Eevelutions or just one?
all of 'em.
But I already had an 80+ link with my espeon so why didn't I get to rank 3.