PokéBase - Pokémon Q&A
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Not unless you get rid of the Leftovers.

ex: Use Fling to get rid of the Leftovers. Then your speed will increase.

See http://pokemondb.net/pokebase/44019/unburden-question

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No,Because leftovers are still on The Pokemon

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>Unburden doubles the Pokémon's Speed stat when the Pokémon's held item is lost. If there is no held item to begin with or if a held item is traded for another, Unburden will not be activated.

Source: Bulbapedia/ Unburden

You don't lose Lefties after using it, so your speed will not increase.

\m/o_o\m/

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