PokéBase - Pokémon Q&A
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Top 5 Highest BST for an unevolved mon (first stage):

  1. Duraludon BST = 535
  2. Type Null: BST = 534
  3. Scyther: BST = 500
  4. Stantler: BST = 465
  5. Basculin : BST = 460
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Dang Scyther's pretty good
Primeape is an evolved Pokemon.
And part of a three stage evolution line
Ah damn sorry bout that
Just to update: Duraludon is now the #1 at 535, as it gained an evolution in Archaludon