Mienshao, U-turn and Baton Pass (105 Speed)
Persian, U-turn (105 Speed)
Persian-Alola, U-turn and Parting Shot (105 Speed)
Lopunny, U-turn and Baton Pass (105 Speed)
Liepard, U-turn and Baton Pass (106 Speed)
Zeraora, Volt Switch (143 Speed)
These are the only options that are above 100 base speed that have Fake Out and a pivoting move besides Raichu. (at least in Galar dex)