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And does the masuda method work?

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Phione isn't one of the Pokémon that are Shiny Locked. So yes, you can breed for a Shiny.

I would imagine Masuda Method works, why wouldn't it?
EDIT: It works.

Source

Hope I helped!

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That’s cool, thanks!
I don't see how that link is definitive evidence for it being particularly helpful for Masuda breeding, it could have been shiny anyway, but again, why wouldn't it? (heh)