PokéBase - Pokémon Q&A
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I thought this was already asked before but I can't find the question. We can keep this one as a reference.

1 Answer

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Best answer

Only two: Articuno who can learn Sheer Cold and Mind Reader, and Smeargle who can learn every move.

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Can I do this in soul silver?
Yes you can.
remember mew
actually, yoshi, mew can't learn EVERY move. Mew can only learn all the TM's,  all the shard / bp moves, and all the level-up moves it has. for example, it can't learn sketch or draco meteor or horn drill.
>Poliwrath, alongside Smeargle and Articuno, is one of the few Pokémon that can learn an accuracy-focusing move and a OHKO move, learning **Fissure by TM27 in Generation I** and **Mind Reader at level 51 in Generation II.**

>It no longer has the ability to learn both moves, however.

Source: [Bulbapedia/ Poliwrath][1]
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I know this question is old, but i saw this and thought it might be useful.

  [1]: http://bulbapedia.bulbagarden.net/wiki/Poliwrath_%28Pok%C3%A9mon%29#Trivia