PokéBase - Pokémon Q&A
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I'm thinking of breeding my Raichu. I don't want to waste my times looking for a compatible Pokémon, so I'm thinking of using a Ditto, and not to get off subject, I need a Light Ball for Volt Tackle. Is there any place for where I can find one?

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1 Answer

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There is a 5% chance a wild Pikachu will be holding a Light Ball when you capture it.
You can find wild Pikachu in Santalune Forest and on Route 3 in Pokemon X and Y.

Hope I helped!

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Additionally, you can lead with something that has Frisk to see if the Pikachu is holding anything, or Compoundeyes to increase the chances of finding a Pikachu w/ Light Ball.