PokéBase - Pokémon Q&A
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Self explanatory

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Azurill
Basculegion
Bellossom
Blaziken
Bonsly
Buizel
Chatot
Deoxys
Donphan
Duskull
Electivire
Elekid
Giratina
Gogoat
Greninja
Helioptile
Ho-Oh
Hoothoot
Kecleon
Latias
Latios
Ledyba
Lotad
Lucario
Lugia
Lycanroc
Magearna
Manaphy
Mantyke
Marill
Mewtwo
Mime Jr.
Munchlax
Noivern
Pelipper
Seedot
Sharpedo
Shaymin
Shroomish
Slowking
Snubbull
Sylveon
Terapagos
Togepi
Volbeat
Wailmer
Weavile
Wingull
Wynaut
Wyrdeer
Zigzagoon
Zoroark
Zorua
Zygarde

Pokémon that appeared in the anime before their game debut (Bulbapedia)

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theres quite alot but the only few I can remember are chatot,buizel,lucario,zorua,zoroark and ho-oh

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On my account, you could play enough of the current version to see a Pokemon before it appears in the show, this accounts for all current Pokemon. The only Pokemon that I could remember seeing before I saw it in the game(s) was Spearow of the very first episode of Pokemon, excluding Pikachu.

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chatot,buizel,lucario, and zoura