PokéBase - Pokémon Q&A
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Non-repeatable
- From an Ace Trainer in the building north of the Pokemon Center
- East of the northern sand pile on Relic Castle's B4F

Repeatable
- Pickup (Starting from Level 31)
- Join Avenue Antique Shop
- 5% chance from wild Solrock
- Dust clouds in caves
- Hidden Grottoes (Route 6, Route 13, Abundant Shrine; 0.25% chance)

Sun Stone (Bulbapedia)

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In Nimbasa city, to the right of the house behind the pokecenter.

Source- Experience

Wither-

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