PokéBase - Pokémon Q&A
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No, you get Premier Balls by Buying 10 or more regular Pokéballs at the pokémart and thats the onlt way unless you trade and get a pokemon holding a Premier Ball...

Source: Experience


hope this helps!!! :D

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oh... :)
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No,
Premier Balls Can Only Be Obtained By Buying 10 Poke'balls.
>Source: Bulbapedia/Premier Balls

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