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And what items do each of them buy?

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In Iccirus City Pokemon Center, there's a rock collector who will buy any rocks for double the price.

On Route 5, there's a caravan with a woman who will buy food items for double the price.

On Route 18, there's a house with a guy who will buy Rare Bones for double.

In Undella Town, in a big house, there's a guy who will buy the Relic items hidden in the underwater place for double. This brings in really big bucks. (total over a million)

And of course, Poke-Mart!!!

Hope this helps!

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good answer to get the relic items you need to dive into abylis ruins i think its called
Something like that...