Or is not a critical capture then? I mean, if the ball stopped mid-air and all, could the Pokemon still escape?
I am curios.
A totally new mechanic of capture is the Critical Capture. This feature works like Critical Hits in battle where there is a slight chance that this feature occurs. Critical Capture will be noticed when you throw the Pokéball. It'll pause in mid-air and make a metal noise. When it hits the Pokémon, it will shake once and capture. This cuts two of the four random calculations out of the overal capture mechanic making it more likely to capture the Pokémon. However, it can still fail.
-Serebii So yes, it can still fail. http://serebii.net/blackwhite/capture.shtml
Well if it failed it technically wouldnt be a capture, but the ball can fail to capture a poke once it shakes resemblimg the shaking of a critical capture.