I personally think that Hoopa-U will be better in doubles, atleast more than singles.
Its signature move breaks through protect which is everywhere in doubles but barely in singles (except on toxic stall). And U-turn while still fairly common in doubles, is not as common as singles.
It is too slow for its horrible defence but it can be useful (more useful than singles). One set that I liked was Choice Specs-Expanding Force with minimum speed alongside TR Indedee in DUU.