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I have a Muk with Acid Armor and been trying the Mirror Herb method with no success. Do I need a Skrelp with Acid Armor or is chain breeding really the only way?

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Goodra doesn't get Acid Armor as an Egg Move in Gen 9. The only way to have it learn Acid Armor is to use Move Relearner while it's still a Sligoo.

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Hope I helped.

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