PokéBase - Pokémon Q&A
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the last three ones in this picture and the one under the Moon Ball (2 down from Ultra Ball)

http://archives.bulbagarden.net/media/upload/5/5b/Allballs2.png

are they from unova? also how do you get them?

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Cherish balls(the red ones) are only obtainable by events & are the pokeballs that give-away pokemon are caught in. Dream balls (the last one) are like master balls that only work in the dream world.

EDIT- The yello one (before last) is a friend ball & it is used In the pal park in d/p/pt/SS/hg & always catch the pokemon in the pal park. The one under the moon ball is the gs ball (i think) & is unobtainable in the games, it is an anime ball used to catch Celebi that was to be delivered from proffessor elm to professor oak by ash.

Hope this helps :)

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Good job.
Sorry my computer froze & then it made what I had typed an answer. I was going to add more & I have.
Ah, okay. Thanks for editing.
i don't think that's the GS ball as it is Orange and has GS written on it also but thanks.
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One is a Cherish Ball that you get via Wi-Fi events and another is a Dream ball that you get from Entree Forest

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thanks, but this should probably be a comment since this only answer half the question.