PokéBase - Pokémon Q&A
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Well for instance I use the island scan feature to find a Totodile on Melemele Island. Can I use the method to make it call allies to possibly chain for a shiny, hidden ability and such.

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Nope

According to all of the Serebii pages of all of the Island Scan only Pokemon, they cannot call for help.

Hope I could help!

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