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In Pokemon platinum (and possibly diamond and pearl too), the exp share is an item that a Pokemon needs to hold. In XY/ORAS, it is a key item that just needs to be turned on or off. Lets say I have a holding the exp. share in platinum, and I poketransfer, then pokebank that into XY/ORAS. What would happen to the exp. share and how would it work.

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The transfer wouldn't work.

You cannot transfer items over PokeBank!

Source: Experience

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