PokéBase - Pokémon Q&A
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Yes.

According to here, Dire Hit increases your critical chance by 1 stage, and Focus Energy increases it by 2 stages. Since this is +3, your Pokemon will always critically hit (Gen 6) or have a 33.3% chance of critically hitting (Gen 2-5)

Source: Above Link

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It literally says that this combination does NOT stack.
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Yes, but only from one source. They do not stack. Dire hit is just an alternate Focus Energy.

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