In X & Y, yes. Once you have fully EV trained a Pokemon (including those 4 EVs) you gain access to Secret Training, where you can get the evolutionary stones and wings.
Otherwise, not really, but 4 EVs can be the difference between 1 HP and 0 HP, since 4 EVs boost a stat by 1. That and the EVs are always nice to have.
Also, if you are splitting EVs, say 252 Speed, 128 SpAtk and 128 SpDef, that uses 2 of the 4 EVs.