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The very 1st pikachu has a very distinct and noticeable feature and extremely hard to find and only manufactured for a short time. 1995-1996- pikachu being the icon of the franchise has black plastic eyes and plastic rosey cheeks and is almost impossible to find only 1 so far has surface on the web and is now being auctioned on ebay. The tag will have blue and yellow logo with its catch phrase"gotta catchem all" and nintendo stamp.

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This cute little thing here - it was between five to seven inches, and was released on 16 June, 1999. After the release of Pikachu, a plush Meowth, Gengar and Psyduck was released the following year in 16 February, 2000 again, between five to seven inches.

Hope I helped. :)
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Note: I'm still looking into this. There may be an earlier release of a plush toy, note that. I'm still checking. :3

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I knew it! Pikachu is some of main character beside Ash! Did there a Mew and Celebi plushie yet?