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If I remember correctly I think that it is found in boundaries cross, but I'm not sure.

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You find the Rare Candy in the POP (Pokemon Organized Play) Series 8 Booster Pack.
POP Series 8 Booster Packaging. enter image description here
POP Series 8 Booster Packaging and Rare Candy Card.
Extra Information on POP Series 8

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Thanks :D
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  • EX Sandstorm
  • EX Emerald
  • EX Holon Phantoms
  • POP Series 5
  • Great Encounters
  • POP Series 8
  • Unleashed
  • Dark Explorer

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Dark Explorers was the one I was thinking of but I thought it was boundries crossed xD