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Which moves?

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Best answer

It frees you from these moves:
Bind
Clamp
Fire spin
Leech Seed
Magma storm
Sand tomb
Spikes
Stealth Rock
Toxic Spikes
whirlpool
Wrap

Keep in mind it has no effect if the foe is a ghost type or if the move misses.

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Thanks for the answer!!
Do both spikes(normal + toxic) work simultaneously
Yes. So you can lose up to 1/4 of your health, then get badly poisoned (assuming to TS were set up) that doesn't include the common stealth rock.
You can have all Entry Hazards set up at the same time, Spikes, Toxic Spikes, Stealth Rock.