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I'm trying to chain a shiny Floatzel or Buizel and I was wondering what places are the encounter rate the highest for either of these Pokemon?

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The single highest place for either is to find a floatzel in route 222 but only in night. The chance is 40%.
Source: http://bulbapedia.bulbagarden.net/wiki/Sinnoh_Route_222

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Valley Windworks is a good place to catch Buizel.
Source: Experience and the Pokemon Platinum Version Game Guide.

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