PokéBase - Pokémon Q&A
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2 Answers

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You can buy them in the Veilstone City department store or trade for them with the underground guys.

Source: http://www.psypokes.com/dp/undergrounditems.php and Experience

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oh yeah, forgot about that
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You buy them with spheres you dig up or buy them at the Veilstone City Department store.(Credit to SuperTyphlosion) This will help.

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Hey! I just clicked on the "This will help" link on your answer. It doesnt exist!
just noticed that
fixed it