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as said above...

would
ev training shuckle in defences make it almost immortal?

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No Pokemon is immortal •_•
If you train Shuckle in Def / SpD, it would make it hard to take down, but don't forget the HP stat. I suggest: 252 HP /128 Def / 128 SpD. If you go with Smogon.... then: 252 HP / 4 Def / 252 SpD

You have to rely on Toxic or some status to actually take down your opponent, since Shuckle has horrible Attack and Special Attack.
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Shuckle mosesets

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Wonder Guard Sableye has something to say about that.
Wonder Guard Sableye is for noobs...
You can take down Wonder Guard Sableye. Remember Will-O-Wisp and Toxic?
What about Power Split?
thanks a lot and as immortal i mean like so undestructable. maybe no moves could 1HKO