Specifically Poochyena!
Dark, Bug and Ghost type moves will boost its speed.
It's not technically scaring, it just raises your Speed Stat if the move that hits you during battle are Dark, Ghost, or Bug types. All Pokemon that learn this are here:
http://www.google.com/m/url?ei=wCaoTfjRK5LWlQeojO27AQ&q=http://bulbapedia.bulbagarden.net/wiki/Rattled_(ability)&ved=0CBMQFjAA&usg=AFQjCNFYnRlpqsfndptNSmdvytXzJpzecw